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Expert Answer: Aniline and benzylamine can be distinguished by their reactions with the help of nitrous acid, which is prepared from a mineral acid and sodium nitrite. The rate of a reaction quadruples when the temperature changes from 293 K to 313 K. Calculate the energy of activation of the reaction assuming that it does not change with temperature. Copyright Notice © 2020 Greycells18 Media Limited and its licensors. Calculate the mass of a non-volatile solute (molar mass 40 g mol-1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%. This video explains the relationship between Cell edge and radius of atoms ... Stoichiometric and non - stochiometric defects in solid, define semiconduc... Queries asked on Sunday & after 7pm from Monday to Saturday will be answered after 12pm the next working day. Relation between cell edge & distance between atoms. Kindly Sign up for a personalized experience. All Rights Reserved. Upvote if u find it useful. Calculate the mole fraction of benzene in solution containing 30% by mass in carbon tetrachloride. Benzylamine reacts with nitrous acid to form unstable diazonium salt, which in turn gives alcohol with the evolution of nitrogen gas. Convert aniline into the following compounds. Give two reactions that show the acidic nature of phenol. (i) N – phenyl benzamide (ii) Phenyl isothiocyanate (iii) 2, 4, 6 – tribromo aniline, Amongst the following, the most basic compound is (a) benzylamine (b) aniline. It ignites readily, burning with a smoky flame characteristic of aromatic compounds. Write the reactions of (i) aromatic and (ii) aliphatic primary amines with nitrous acid. How aniline is prepared from (1) benzamide (2) Benzoic acid (3) Nitrobenzene asked Mar 16, 2019 in Chemistry by Akhil001 ( 1.4k points) Welcome to Sarthaks eConnect: A unique platform where students can interact with teachers/experts/students to get solutions to their queries. A 5% solution (by mass) of cane sugar in water has freezing point of 271 K. Calculate the freezing point of 5% glucose in water if freezing point of pure water is 273.15 K. Calculate the mass of urea (NH2CONH2) required in making 2.5 kg of 0.25 molal aqueous solution. Action of soap is due to emulsification and micelle formation. The vapour pressure of pure liquids A and B are 450 and 700 mm Hg respectively, at 350 K. Find out the composition of the liquid mixture if total vapour pressure is 600 mm Hg. Copyright © 2020 saralstudy.com. Verify your number to create your account, Sign up with different email address/mobile number, NEWSLETTER : Get latest updates in your inbox, Need assistance? 2.2K views (iii) Ethanamine to N,N-Diethylethanamine. Compare acidity of phenol with that of ethanol. accomplish the following conversions i nitro... What type of bonding helps in stabilising the ∝-helix structure of proteins? Why cannot aromatic primary amines be prepared by Gabriel phthalimide synthesis? The oxidation number of cobalt in K[Co(CO)4] is, Your questions and answers is more helpfull to a learner but what i suggest try to make a short paragraph on each quetion answered so dhat a learner can get more knowledge on what he or she need to read more,,thanks for your contribution. Students (upto class 10+2) preparing for All Government Exams, CBSE Board Exam, ICSE Board Exam, State Board Exam, JEE (Mains+Advance) and NEET can ask questions from any subject and get quick answers by subject teachers/ experts/mentors/students. The benzene is first converted to nitrobenzene which is in turn reduced to phenylamine. Want a call from us give your mobile number below, For any content/service related issues please contact on this number. Or u can Use NaOH+Br2 to convert Benzamide into Aniline then treat it with HNO2 followed by HCN/CuCN to convert it into Benzene cyanate then treat it with H2/Pd. Henry's law constant for CO2 in water is 1.67 x 108Pa at 298 K. Calculate the quantity of CO2in 500 mL of soda water when packed under 2.5 atm CO2 pressure at 298 K. How the following conversions can be carried out? Predict the products of the following reactions: Why do we need to classify drugs in different ways? Step-2:—Conversion of benzamide to aniline. Benzamide to aniline: (c) from nitrobenzene: Nitro compounds on reduction with hydrogen gas in the presence of finely divided nickel , palladium or platinum and on reduction with metals in the acidic medium give amines. MAKING PHENYLAMINE This page looks in outline at the preparation of phenylamine (also known as aniline or aminobenzene) starting from benzene. General Principles and Processes of Isolation of Elements. Distinguish between the following pair of compounds: (i) Aniline and Benzylamine. Mention the conditions required to maximise the yield of ammonia. If the solubility of H2S in water at STP is 0.195 m, calculate Henry's law constant. How aniline is prepared from (1) benzamide (2) Benzoic acid (3) Nitrobenzene. 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